• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    The present invention relates to a fire retardant composition for use in wood composite panels, said composition comprising - at least one fire retardant selected from the group of ammonium (poly) phosphates, ammonium sulfate, ammonium chloride, ammonium sulfamate, guanidine phosphate, guanindine sulfamate and alkaline earth phosphates where the total concentration of said smoke suppressant in the composition is between 25 and 100% in dry weight of said composition, - optionally at least one smoke suppressant, wherein the total concentration of smoke suppressant is between 0 and 25% in dry weight of said composition; and - a pH-regulating compound, characterized in that the pH of a 10% aqueous solution of the said composition is between 3.5 and 7.5.
    公开号:BE1024861B1
    申请号:E2017/5166
    申请日:2017-03-17
    公开日:2018-07-30
    发明作者:Helmut Wiehn；Barbora Deppe；Herman Meynaerts；Pieter Daeseleire
    申请人:Ecochem International, Naamloze Vennootschap；
    IPC主号:
    专利说明:

    Holder:
    ECOCHEM INTERNATIONAL, a public limited company
    2250, OLES
    Belgium
    Inventor:
    WIEHN Helmut
    76831 HEUCHELHEIM-KLINGEN Belgium
    DEPPE Barbora
    77654 OFFENBURG Germany
    MEYNAERTS Herman 2250 OLEN Belgium
    DAESELEIRE Pieter 2250 OLEN Belgium
    FIRE-RETARDANT COMPOSITION FOR USE IN WOODEN COMPOSITE PANELS
    The present invention relates to a fire retardant composition for use in wood composite panels, said composition comprising - at least one fire retardant selected from the group of ammonium (poly) phosphates, ammonium sulfate, ammonium chloride, ammonium sulfamate, guanidine phosphate, guanindine sulfamate and alkaline earth phosphates in which the total concentration of said smoke suppressant in the composition is between 25 and 100% in dry weight of said composition, - optionally at least one smoke suppressant, wherein the total concentration of smoke suppressants is between 0 and 25% in dry weight of said composition; and - a pH controlling compound, characterized in that the pH of a 10% aqueous solution of said composition is between 3.5 and 7.5.
    BELGIAN INVENTION PATENT
    FPS Economy, K.M.O., Self-employed & Energy
    Intellectual Property Office
    Publication number: 1024861 Filing number: BE2017 / 5166
    International classification: C09K 21/04 Date of issue: 30/07/2018
    The Minister of Economy,
    Having regard to the Paris Convention of 20 March 1883 for the Protection of Industrial Property;
    Having regard to the Law of March 28, 1984 on inventive patents, Article 22, for patent applications filed before September 22, 2014;
    Having regard to Title 1 Invention Patents of Book XI of the Economic Law Code, Article XI.24, for patent applications filed from September 22, 2014;
    Having regard to the Royal Decree of 2 December 1986 on the filing, granting and maintenance of inventive patents, Article 28;
    Having regard to the application for an invention patent received by the Intellectual Property Office on 17/03/2017.
    Whereas for patent applications that fall within the scope of Title 1, Book XI, of the Code of Economic Law (hereinafter WER), in accordance with Article XI.19, § 4, second paragraph, of the WER, the granted patent will be limited. to the patent claims for which the novelty search report was prepared, when the patent application is the subject of a novelty search report indicating a lack of unity of invention as referred to in paragraph 1, and when the applicant does not limit his filing and does not file a divisional application in accordance with the search report.
    Decision:
    Article 1
    ECOCHEM INTERNATIONAL, public limited company, Industrielaan 25, 2250 ÖLEN Belgium;
    represented by
    BRANTS Johan Philippe Emile, Pauline Van Pottelsberghelaan 24, 9051, GHENT;
    a Belgian invention patent with a term of 20 years, subject to payment of the annual fees as referred to in Article XI.48, § 1 of the Code of Economic Law, for:
    FIRE-RETARDANT COMPOSITION FOR USE IN WOODEN COMPOSITE PANELS.
    INVENTOR (S):
    WIEHN Helmut, Hauptstr. 77, 76831, HEUCHELHEIM-KLINGEN;
    DEPPE Barbora, Zur Lindenhöhe 8A, 77654, OFFENBURG;
    MEYNAERTS Herman, Industrielaan 25, 2250, ÖLEN;
    DAESELEIRE Pieter, Industrielaan 25, 2250, ÖLEN;
    PRIORITY:
    30/12/2016 BE BE2016 / 5996;
    BREAKDOWN:
    Split from basic application: Filing date of the basic application:
    Article 2. - This patent is granted without prior investigation into the patentability of the invention, without warranty of the Merit of the invention, nor of the accuracy of its description and at the risk of the applicant (s).
    Brussels, 30/07/2018,
    With special authorization:
    BE2017 / 5166
    FIRE-RETARDANT COMPOSITION FOR USE IN WOODEN COMPOSITE PANELS
    TECHNICAL AREA
    The present invention relates to the technical field of fire retardant compositions for use in wood composite panels.
    BACKGROUND
    Wood composite panels are widely used in the construction industry. Both wood and these wood-based materials must meet high requirements for refractory properties. Various standards and requirements have been introduced in Europe that allow the fire properties of building materials to be compared (eg Euroclass EN 13501-1). Characteristics such as almost non-flammability, flammability, flame spread, calorific value as well as the development of smoke and burning droplets of the material are taken into account when classifying a building material in these classes.
    In order to meet these requirements and to meet the highest quality standards, composite panels are often supplemented during their production with compositions with fire retardant properties and optional smoke suppressors.
    For example, US 8 715 540 describes a fire retardant composition for reducing the amount of fire that occurs on a material as well as the smoke density that is produced. The composition can be added to building material.
    EP 2 586 849 is directed to an aqueous composition containing MAP as a flame retardant. The composition is used in the production of wood composite panels to create fire retardant wood composite panels.
    The production of these wood composite panels usually uses an adhesive or resin to provide cohesion to the wood particles or fibers. The addition of additives such as fire retardant compositions can have an impact on the functionality of these resins (eg lower bond strength). Consequently, larger amounts of resin are sometimes required to ensure good cohesion of the good quality articles and finished products.
    BE2017 / 5166 consequently
    Thus, there is a need for an improved way of producing fire retardant and smoke suppressing wood composite panels, as well as a need to better perform fire retardant / smoke suppressing compositions. The present invention aims to provide a solution to this.
    SUMMARY OF THE INVENTION
    The present invention provides a fire retardant composition according to claim 1. This composition is particularly useful for use in wood composite panels. The pH of the composition is carefully adjusted through the addition of one or more pH controllers to provide good compatibility with the resins used in the production of the wood composite materials. In addition, the pH can be further controlled based on the specific resin used during production. By controlling the pH of the fire retardant composition to a very specific and predetermined range, the inventors of the present invention have found that the bond strength of the resin was positively influenced. This even resulted in lower resin consumption, which in turn has a positive impact on cost.
    The compositions of the present invention can be used as a dry particulate matter (e.g. powder or granulate) or in a liquid form such as a solution or a dispersion.
    In a second aspect, the present invention provides a specific use of the composition in the production of fire retardant wood composite panels according to claim 10 as well as the resulting panels according to claim 14. The resulting panels meet various fire retardant standards (ASTM, EN, DIN, BS, NF, P) for construction products.
    DETAILED DESCRIPTION OF THE INVENTION
    The present invention relates to a fire retardant composition for use in wood composite panels.
    Unless otherwise defined, all terms used in the description of the invention, including technical and scientific terms, have the meaning generally understood by one skilled in the art to which this invention pertains. Furthermore, the definitions of the terms are included to better understand the description of the present invention.
    As used here, the following terms have the following meanings:
    One, the and the as used here refer to both the singular and the plural unless the context indicates otherwise. A compartment refers, for example, to one or more than one compartment.
    Approximately as used herein, which refers to a measurable value such as a parameter, an amount, a time period and the like, is intended to include variations of +/- 20% or less, preferably +/- 10% or less, more at preferably +/- 5% or less, even more preferably +/- 1% or less, and even more preferably +/- 0.1% or less of the specified value, to the extent that such variations are suitable to perform in the described invention. It will be understood, however, that the value to which the modifier relates approximately is itself also specifically described.
    Include, comprising and includes and consisting of as used herein are synonymous with contain, contain or contain and are inclusive or open terms that specify the presence of what follows e.g. a component and exclude the presence of additional, unlisted components, features do not eliminate elements, parts, steps which are well known in the art or described therein.
    Claiming numerical ranges by endpoints includes all cases and fractions included within that range, as well as said endpoints.
    The terms weight%, weight percent,% wt. or% by weight, throughout and throughout the description unless otherwise noted, refer to the relative weight of the respective component based on the total weight of the formula. The expression% in dry weight of the composition is to be understood as the relative weight of the respective component based on the total dry matter weight of the formula.
    The term wood composite panels refers to a range of derived wood products produced by bonding or fastening the strands, particles, fibers or veneers or wood boards, together with adhesives, bico-fiber resins, to form composite materials. Engineered wood products are usually made from the same types of heartwood and softwood that are used to produce lumber. Wood saw waste and other wood waste can be used for engineered wood consisting of wood particles or fibers, but whole blocks are usually used for veneer wood, such as laminated wood, MDF or chipboard. Some engineered wood products, such as oriented strand board (OSB), can use trees of the poplar family, a common but non-structural species.
    Alternatively, it is also possible to produce similarly engineered bamboo from bamboo; and similarly engineered cellulose products from other lignin-containing materials such as rye straw, wheat straw, rice straw, hemp straws, kenafs or sugarcane residue, in which case they do not contain real wood, but rather vegetable fibers.
    Wood composite panels may therefore include, but are not limited to, the following: laminated wood, fiberboard, oriented strand board (OSB) laminated wood or veneer, chipboard, sheet material or medium density fiberboard, HDF, or wood fiber insulation.
    The term dry as used herein in connection with a composition of the invention, or with individual components of a composition of the invention, means that water, and other aqueous and non-aqueous liquids, are not an ingredient or component of the composition, but that the dry composition may or may not contain any moisture. The amount of moisture that may be present in a dry composition of the invention is preferably less than about 1 weight percent, more preferably less than 0.5 weight percent, and more preferably less than about 0.1 weight percent, and most preferably about 0 weight percent. A dry composition according to the invention can be, for example, in the form of a powder, granules, particles, pellets and / or the like. The various forms that dry compositions can take are well known to those skilled in the art.
    The term aqueous, as used herein in connection with a composition of the invention, means that the composition is at least partially dissolved in a solvent such as water, or that a dispersion has been produced.
    The term composition as used herein means a product that results from the combination of more than one ingredient.
    The term fire retardant as used herein is to be understood as an agent which, when added to the wood composite material, may provide fire retardant properties to said material. Fire retardancy is defined as the reduction of energy release, flame propagation and rate of flame propagation during a fire.
    The term smoke suppressant is to be understood as an agent which, when added to a wood composite material, may reduce the smoke production or density of the material when heated or burned.
    In a first aspect, the invention provides a fire retardant composition for use in wood composite panels, said composition comprising at least one fire retardant, a pH controlling compound and optionally a smoke suppressant, wherein the pH of a 10% aqueous solution of the said composition is between 3.5 and 7.5, more preferably between 4 and 7.
    The inventors of the present invention have found that by controlling the pH of the composition to a narrow and predefined range using pH control compounds, optimum compatibility is obtained with the resins used during the production of the wood composite panels. The pH of the composition is determined in a 10% aqueous solution of the composition, which allows standardization among all compositions within the scope of the present invention. The pH can be measured by any suitable method well known in the art. The pH is preferably measured with a potentiometer.
    Said fire retardant is preferably selected from the group consisting of ammonium (poly) phosphates such as monoammonium dihydrogen phosphate (MAP), di-ammonium hydrogen phosphate (DAP, both for technical use and as a fertilizer) or ammonium polyphosphate (with different chain lengths); ammonium sulfate; ammonium chloride; ammonium sulfamate; guanidine phosphate; guanidine hydrogen phosphate; guanidine sulfamate; methylene urea and alkaline earth phosphates or any mixture thereof.
    The total concentration of the fire retardant in the composition is preferably between 25 and 100% in dry weight of said composition, more preferably between 25 and 98% in dry weight of said composition. Below this ratio, the composition will not provide sufficient fire retardant protection when added to wood composite products.
    In one embodiment, said one or more fire retardant means only act as a fire retardant. In another embodiment, said fire retardants may have a dual function, and may also act, for example, as a pH controlling compound. This is especially the case when a high concentration of pH controlling compound is required to fall within the desired pH range of the present invention. When the concentration of the pH-controlling compound is higher than a total concentration of 10% in dry weight of the composition, it is usually ensured that a pH-controlling compound is chosen which simultaneously offers fire-retardant and / or smoke-suppressing activity within the composition, to prevent a less active composition. Examples of dual action pH controlling compounds are, for example, monoammonium or di-ammonium phosphate. When the latter is used to control the pH, a second flame retardant will always be present in the composition.
    The said pH-adjusting compound can preferably be selected from the group consisting of mono-dihydrogen or di-ammonium hydrogen phosphate (both for technical use and as a fertilizer), ammonium or aluminum sulfate, magnesium phosphate, monoethanolamine, phosphoric acid, sulfamic acid, magnesium phosphate, mono or dicalcium phosphate, ammonium or ammonium solution, or any mixture thereof.
    The amount of the pH controlling compound to be added to the composition is thus determined such that the pH of the final composition, when in a 10% aqueous solution, is between 3.5 and 7.5, more at preferably between 4 and 7.
    The total concentration of said pH controlling compounds is preferably between 2 and 50% by dry weight of the composition. As mentioned, when the total concentration of the pH controlling compound is greater than 10%, it will be chosen to use a pH controlling compound which has a dual function, either as a fire retardant or as a smoke suppressant or both, to ensure the activity of the composition in terms of fire retardant (and smoke suppressing) activity.
    The composition of the present invention may optionally comprise a smoke suppressant, which is preferably present in a total concentration of between 0 and 40% by dry weight of said composition; more preferably between 0 and 25% in dry weight of said composition, even more preferably in a concentration between 1 and 20% in dry weight of said composition.
    Said smoke suppressant, when present, is selected from the group of borate minerals, boric acid or a salt thereof such as zinc borate, borax (decahydrate or pentahydrate), disodium octaborate (anhydrous or tetra hydrate); calcium or magnesium phosphates (e.g. monocalcium phosphate, dicalcium phosphate) and magnesium hydroxide or a mineral thereof such as brucit; or any mixture thereof.
    Borate minerals are preferably ulexite, colemanite, kernite, howlite or probertite. The inventors of the present invention have found that these minerals have a good smoke suppressing function. Due to their natural nature, they exhibit no or only very low toxicity which makes them particularly useful for use in the fire retardant composition of the present invention. Consequently, these minerals are good alternatives to e.g. more toxic smoke suppressants such as boric acid or disodium octaborate (DOT) or can be used to reduce the amount of these components when they are present in the fire retardant compositions of the present invention.
    The composition of the present invention may further comprise a detection compound and / or an antimicrobial or antifungal compound.
    The said detection compound can be understood as a label, in an amount sufficient to allow determination by one or more detection processes before and after a material has been exposed to flame or fire (or other burning materials), or that a composition according to the invention it may or may not be applied to the material before the material has been exposed to the flames or fire (or other burning material), and if so, whether the composition has been properly applied to the material.
    Antimicrobial and / or antifungal composition can be understood as any substance that can inhibit growth of microorganisms such as bacteria or phantom in the wood composite panels when treated with the composition of the present invention.
    In one embodiment, said composition is a particulate dry matter such as a powder or (micro) granulate form or other dry granular, milled, pulverized or otherwise finely dispersed solid particles, uncompressed (ie in loose form) or compressed to produce a solid structure, such as a solid structure in the form of a pill, powder, pellet, stick or the like.
    For powders, preferably at least 90% of the particles contained in the composition will have a particle size less than 200 µm. In another or further embodiment, preferably at least 90% of the particles present in the composition, when in a dry formula, will have a particle size of less than 60 µm. More preferably, at least 70% of the particles will have a particle size of less than 40 µm.
    When micro granulates are used, at least 80% of the particle size will be greater than 200 µm, but will preferably not be larger than 800 µm.
    Particle size determination methods are well known in the art. A particularly suitable method is laser diffraction.
    The said composition may also be in a liquid form, such as a dispersion or suspension, a solution, an emulsion or a slurry. Water is preferably used as a solvent.
    Such liquid can be obtained by using a particulate dry matter composition of the present invention and thereby can produce an aqueous solution, dispersion or slurry. This could happen, for example, at the site where the wood composite panels are produced, just before adding the composition to the production line. Another possibility is the ready-to-use production of a dispersion according to an embodiment of the present invention, by means of one or more tanks provided with a mixing device suitable for making a dispersion. The components of the composition of the present invention are added to a mixing tank with the addition of water, after which an aqueous solution or dispersion is made.
    When used as a dispersion, the composition of the present invention may further comprise a thickener and / or viscosity controller and / or wetting agent. Said thickener may be an organic or inorganic thickener for adjusting the viscosity of the dispersion to a predefined viscosity target. Suitable organics include cellulosic material and gums such as xanthan gum. When very fine dispersions are achieved, inorganic thickeners such as, but not limited to, clay thickeners such as bentonite or sepiolet thickeners are suitable for the present invention. The addition of these compounds prevents the precipitation of particles in dispersions of the present invention, thereby extending the shelf life of the compositions.
    Compositions of the present invention, whether in dry or liquid form, are particularly suitable for use in wood composite panels. These panels are produced by bonding or fastening strands, particles, fibers or veneer or chipboard, together with adhesives or resins, to form composite materials. Fire retardants and smoke suppressants are added during the production process of these panels, either as a dry composition or as a liquid (solvent or dispersion).
    The inventors of the present invention have now found that the pH of the compositions of the present invention has a large influence on the behavior of the resins used. It has been found to have a pH of 3.5 to 7; more preferably 4 to 7, ensures optimum compatibility with the resins, and positively affects the functionality of these resins (such as internal bond strength). The amount of the resin used can therefore even be reduced; therefore, the present invention also results in a cost effective aspect.
    In addition, the inventors of the present invention have found that the pH of the composition can be further specified depending on the type of resin used.
    When melamine urea formaldehyde (MUF) or urea formaldehyde (UF) is used as a resin in the production of wood panels, the pH of a 10% aqueous solution of the composition according to any of the aforementioned embodiments is between 5 and 7.
    When a polymeric isocyanate or isocyanate prepolymer is used as a resin, the pH of a 10% aqueous solution of the composition according to any of the aforementioned embodiments is between 4 and 6, such as e.g. 4,6 or 5.
    7/5166
    Said panels produced by addition of a composition of the present invention are preferably medium density fiberboard (MDF), HDF, oriented Strandboard (OSB), fiberboard or wood fiber insulation products. Accordingly, the present invention also relates to such panels having the fire retardant composition as described herein.
    Examples
    The invention is further explained by examples which should not be considered as limiting the scope of the present invention.
    Composition specifically suitable for use in sane plates
    MAP (monoammonium dihydrogen phosphate) 90%
    MCP (monocalcium phosphate) 5%
    DCP (dicalcium phosphate) 2.5%
    Ulexite (sodium calcium borate) 2.5% pH of a 10% solution of the composition is 4.5
    Composition specifically suitable for use in MDF
    MAP (monoammonium dihydrogen phosphate) 42.5% DAP (diammonium hydrogen phosphate) 42.5%
    MGP (magnesium hydrogen phosphate) 10%
    Ulexite (sodium calcium borate) 5% pH of a 10% solution of the composition is 6.2
    权利要求:
    Claims (14)
    [1]
    CONCLUSIONS
    BE2017 / 5166
    1. Fire retardant composition for use in wood composite panels, said composition comprising:
    - at least one flame retardant selected from the group of ammonium (poly) phosphates, ammonium sulfate, ammonium chloride, ammonium sulfamate, guanidine phosphate, guanidine hydrogen phosphate, guanindine sulfamate, methylene urum and alkaline earth phosphates, the total concentration of said fire retardant being in the composition 100% in dry weight of the said composition,
    - optionally at least one smoke suppressant, the total concentration of smoke suppressants being between 0 and 25% in dry weight of said composition; and
    - a pH-controlling compound, characterized in that the pH of a 10% aqueous solution of the said composition is between 3.5 and 7.5.
    [2]
    The fire retardant composition according to claim 1, wherein said smoke suppressant, when present, is selected from the group consisting of borate minerals, boric acid and a salt thereof, calcium or magnesium phosphates and magnesium hydroxide or a mineral thereof.
    [3]
    Fire-retardant composition according to any one of the preceding claims, characterized in that the pH-controlling compound is selected from the group consisting of mono-dihydrogen or di-ammonium hydrogen phosphate (both for technical use and as a fertilizer), ammonium or aluminum sulfate, magnesium phosphate, monoethanolamine, phosphoric acid, sulfamic acid, magnesium phosphate, mono or dicalcium phosphate, ammonium or ammonium solution, or any mixture thereof.
    [4]
    Fire-retardant composition according to any one of the preceding claims, characterized in that the total concentration of said pH-controlling compounds is between 2 and 50%.
    [5]
    Fire retardant composition according to claims 2 to 4, characterized in that said borate minerals are ulexite, colemanite, kernite, howlite or probertite.
    12 BE2017 / 5166
    The fire retardant composition according to any of the preceding claims, wherein said composition is in powder or granular form.
    [6]
    Fire-retardant composition according to any one of the preceding claims, characterized in that said composition is a liquid.
    [7]
    The fire retardant composition according to any one of the preceding claims, further comprising a thickener / or viscosity controller.
    [8]
    Fire retardant composition according to any one of the preceding claims, wherein said composition comprises a detection compound and / or an antimicrobial or antifungal compound.
    [9]
    Use of a composition according to any one of claims 1 to 9 in wood composite panels.
    [10]
    Use according to claim 10, wherein the pH of a 10% aqueous solution of said composition is between 5 and 7 when said panel comprises a (melamine) urea-formaldehyde as a resin.
    [11]
    The use of claim 10, wherein the pH of a 10% aqueous solution of said composition is between 4 and 6 when said panel comprises an isocyanate resin.
    [12]
    Use according to any one of the preceding claims, wherein said panel is medium density fiberboard (MDF) oriented strandboard (OSB), chipboard or fiberboard.
    [13]
    Wooden composite fiberboard consisting of a fire-retardant composition according to any one of the preceding claims.
    [14]
    The wood composite fiberboard of claim 14, wherein said panel is a medium density fiberboard (MDF), HDF, oriented strandboard (OSB), chipboard or fiberboard.
    FIRE-RETARDANT COMPOSITION FOR USE IN WOODEN COMPOSITE PANELS
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    同族专利:
    公开号 | 公开日
    EP3562911A1|2019-11-06|
    CA3046114A1|2018-07-05|
    BE1024861A1|2018-07-24|
    US20190330531A1|2019-10-31|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    US4725382A|1984-04-19|1988-02-16|Chemical Specialties, Inc.|Fire retardant composition|
    WO2002102926A1|2001-06-15|2002-12-27|Adhesives Research Institute Ltd.|Aqueous fire retardant|
    US20210178663A1|2019-12-17|2021-06-17|Goodrich Corporation|Laminated Object Additive Manufacturing for Veneer Applications|
    法律状态:
    2018-10-03| FG| Patent granted|Effective date: 20180730 |
    优先权:
    申请号 | 申请日 | 专利标题
    BE201605996|2016-12-30|
    BEBE2016/5996|2016-12-30|US16/473,686| US20190330531A1|2016-12-30|2018-01-02|Fire retarding composition for use in wood composite panels|
    PCT/EP2018/050056| WO2018122406A1|2016-12-30|2018-01-02|Fire retarding composition for use in wood composite panels|
    EP18700135.9A| EP3562911A1|2016-12-30|2018-01-02|Fire retarding composition for use in wood composite panels|
    CA3046114A| CA3046114A1|2016-12-30|2018-01-02|Fire retarding composition for use in wood composite panels|
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